Standards Sorted by Type

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Molecular Weight Standards, GPC/SEC Calibration Kits and Validation Standards

PSS supplies certified standards that meet the requirements of DIN 55672 and ISO/EN 13885. All reference materials are characterized with GPC/SEC to obtain molecular weight values. These values are subsequently confirmed by alternative methods such as Laser Light Scattering, Viscometry, MALDI-ToF, VPO and NMR.

Each product comes with a Certificate of Analysis, which provides the characterization information, the testing parameters, the molecular weight values (M_n, M_w, M_p, PDI) and the chromatogram. Calibration kits include a calibration report.

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Poly(ethylene glycol)

Order No.	Nominal MW	Description	PDI	Packsize
PSS-pegkit		Kit Poly(ethylene glycol), 10 x 0.5 g, Mp 106 - 44 000 Da
PSS-pegkitval		LCCCValid Validation Kit, 6 x 3 and 3 x 4 Vials-1.5ml
PSS-pegkitvala		LCCCValid Validation Kit, PEG Standards, 10 x 3 Vials-1.5ml
PSS-PEG62	62	Poly(ethylene glycol)	=1,00	1000,00
PSS-PEG106	106	Poly(ethylene glycol)	=1,00	1000,00
PSS-PEG150	150	Poly(ethylene glycol)	=1,00	1000,00
PSS-PEG194	194	Poly(ethylene glycol)	=1,00	1000,00
PSS-PEG200	200	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG238	238	Poly(ethylene glycol)	=1,00	1000,00
PSS-PEG282	282	Poly(ethylene glycol)	=1,00	1000,00
PSS-PEG330	330	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG400	400	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG600	600	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG1K	1000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG1.5K	1500	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG2K	2000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG3K	3000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG4K	4000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG6K	6000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG10K	10000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG12K	12000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG18K	18000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG22K	22000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG26K	26000	Poly(ethylene glycol)	<1,25	1000,00
PSS-PEG42K	42000	Poly(ethylene glycol)	<1,30	1000,00
PSS-pegkitr1		ReadyCal-Kit Poly(ethylene glycol), 3 x 10 Vials-1.5ml, Mp 232 - 44 000 Da

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Poly(propylene glycol)

Order No.	Nominal MW	Description	PDI	Packsize
PSS-PPG76	76	Poly(propylene glycol)	=1,00	1000,00
PSS-PPG192	192	Poly(propylene glycol)	=1,00	1000,00
PSS-PPG790	790	Poly(propylene glycol)	<1,15	1000,00
PSS-PPG450	450	Poly(propylene glycol)	<1,15	1000,00
PSS-PPG3K	3000	Poly(propylene glycol)	<1,15	1000,00
PSS-PPG4.5K	4500	Poly(propylene glycol)	<1,15	1000,00
PSS-PPG1K	1000	Poly(propylene glycol)	<1,15	1000,00
PSS-ppgkit		Kit Poly(propylene glycol), 7 x 1.0 g, Mp 76 - 4 150 Da

Specialties

Product	Download
Random copolymers	A selection of random copolymers with different compositions.
Block copolymers	A large selection of block copolymers with different chemistries and compositions.
Deuterated polymers	A selection of deuterated polymers. Material safety data sheet: SDS
Functionalized polymers	Reference materials with specific end groups or without initiator. Material safety data sheet: SDS
Star polymers	A selection of star branched polymers with 3 arms.

Polydispersity Index, PDI

The Polydispersity Index, PDI, is a measure of the width of the molar mass distribution. It is defined as ratio of the weight average molar mass M_w and the number average molar mass M_n, PDI =M_w/M_n.

PDI is 1 for monodisperse substances (no molar mass distribution), it is larger than 1 for the vast majority of all macromolecules. The PDI depends on the polymerization technique applied to produce the material. In praxis the PDI can be very large up to values of 100 and above. Narrow PDIs can only be obtained using controlled/living polymerization techniques.

Please refer to the literature section to learn more.

Narrow Standards
Broad Standards

Narrow polymer standards are made by controlled/living polymerization techniques (living anionic/cationic, ATRP, RAFT, etc.) or by fractionation of very broad standards.

All narrow standards have small polydispersity indices and exhibit a sharp and slim chromatographic profile.

The M_p value (molar mass at the peak maximum) is well defined and independent on the column resolution. As M_p is the only clearly defined point in the chromatogram this value is used to establish GPC/SEC calibration curves.

Standards with a narrow molar mass distribution are used:

to construct a GPC/SEC calibration curve using the provided M_p values
for the validation of a chromatographic system
for the determining of physical constants

Broad reference materials are made by radical polymerization, polycondensation or coordinative polymerization (polyolefins).

The PDI of broad standards is usually > 1.5. For broad standards the M_p value is a function of the column resolution. Molar mass values provided for broad standards are thus only the average molar masses M_w and M_n.

Modern GPC/SEC software packages allow for the construction of a calibration curve by the use of M_w, M_n or the intrinsic viscosity [η] of broad standards.

Standards with a broad molar mass distribution are used:

to validate a chromatographic system
to determine physical constants such as the Mark-Houwink constants K and ∝
to construct a calibration curve using broad calibration options
to test for porosity mismatch